GHS Hazard Statement

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HAZARD AND PRECAUTIONARY STATEMENTS

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

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GHS.png

Exploding Bomb
GHS01

Unstable explosives
Explosives of Divisions 1.1, 1.2, 1.3, 1.4
Self reactive substances and mixtures, Types A,B
Organic peroxides, Types A,B

Flame
GHS02

Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Flammable solids, categories 1,2
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures, categories 1,2
Substances and mixtures, which in contact with water,
emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F

Description                       Pictogram                            Hazard class and hazard category:

Flame Over Circle
GHS03

Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3

Gas Cylinder
GHS04

Gases under pressure:
- Compressed gases
- Liquefied gases
- Refrigerated liquefied gases 
- Dissolved gases

Corrosion
GHS05

Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1

Skull and Crossbones
GHS06

Acute toxicity (oral, dermal, inhalation), categories 1,2,3

Exclamation Mark
GHS07

Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3

Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1

Hazardous to the aquatic environment
- Acute hazard, category1
- Chronic hazard, categories 1,2

GHS01.png
GHS04.png
GHS07.png
GHS05.png
GHS02.png
GHS03.png
GHS06.png

Health Hazard
GHS08

GHS08.png

Environment
GHS09

GHS09.png
PICTOGRAMS AND HAZARD CODES
 
 
Physical hazards
  • H200      Unstable explosives.

  • H201      Explosive; mass explosion hazard.

  • H202      Explosive, severe projection hazard.

  • H203      Explosive; fire, blast or projection hazard.

  • H204      Fire or projection hazard.

  • H205      May mass explode in fire.

  • H220      Extremely flammable gas.

  • H221      Flammable gas.

  • H222      Extremely flammable aerosol.

  • H223      Flammable aerosol.

  • H224      Extremely flammable liquid and vapour.

  • H225      Highly flammable liquid and vapour.

  • H226      Flammable liquid and vapour.

  • H227      Combustible liquid.

  • H228      Flammable solid.

  • H240      Heating may cause an explosion.

  • H241      Heating may cause a fire or explosion.

  • H242      Heating may cause a fire.

  • H250      Catches fire spontaneously if exposed to air.

  • H251      Self-heating: may catch fire.

  • H252      Self-heating in large quantities; may catch fire.

  • H260      In contact with water releases flammable gases which may ignite spontaneously.

  • H261      In contact with water releases flammable gas.

  • H270      May cause or intensify fire; oxidizer.

  • H271      May cause fire or explosion; strong oxidizer.

  • H272      May intensify fire; oxidizer.

  • H280      Contains gas under pressure; may explode if heated.

  • H281      Contains refrigerated gas; may cause cryogenic burns or injury.

  • H290      May be corrosive to metals.

 
Environmental Hazards
  • H400      Very toxic to aquatic life.

  • H401      Toxic to aquatic life.

  • H402      Harmful to aquatic life.

  • H410      Very toxic to aquatic life with long lasting effects.

  • H411      Toxic to aquatic life with long lasting effects.

  • H412      Harmful to aquatic life with long lasting effects.

  • H413      May cause long lasting harmful effects to aquatic life.

  • H420      Harms public health and the environment by destroying ozone in the upper atmospere.

 
  • EUH001                Explosive when dry.

  • EUH006                Explosive with or without contact with air.

  • EUH014                Reacts violently with water.

  • EUH018                In use may form flammable/explosive vapour-air mixture.

  • EUH018a             In use may form explosive vapour-air mixture.

  • EUH018b             In use may form flammable vapour-air mixture.

  • EUH019                May form explosive peroxides.

  • EUH029                Contact with water liberates toxic gas.

  • EUH030                Can become highly flammable in use.

  • EUH031                Contact with acids liberates toxic gas.

  • EUH032                Contact with acids liberates very toxic gas.

  • EUH044                Risk of explosion if heated under confinement.

  • EUH059                Hazardous to the ozone layer.

  • EUH066                Repeated exposure may cause skin dryness or cracking.

  • EUH070                Toxic by eye contact.

  • EUH071                Corrosive to the respiratory tract.

  • EUH201                Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. Warning! Contains lead.

  • EUH201A             Warning! Contains lead.

  • EUH202                Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.

  • EUH203                Contains chromium (VI). May produce an allergic reaction.

  • EUH204                Contains isocyanates. See information supplied by the manufacturer.

  • EUH205                Contains epoxy constituents. See information supplied by the manufacturer.

  • EUH206                Warning! Do not use together with other products. May release dangerous gases (chlorine).

  • EUH207                Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer.

  • Comply with the safety instructions.

  • EUH207-EG        Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer.

  • Comply with the safety instructions.

  • EUH208                Contains (name of sensitising substance). May produce an allergic reaction.

  • EUH208-EG        Contains (name of sensitising substance). May produce an allergic reaction.

  • EUH209                Can become highly flammable in use.

  • EUH209a             Can become highly flammable in use.

  • EUH209b             Can become flammable in use.

  • EUH209A             Can become flammable in use.

  • EUH210                Safety data sheet available on request.

  • EUH401                To avoid risks to human health and the environment, comply with the instructions for use.

European Union Hazard Statements
 

Precautionary statements - General

  • P101 If medical advice is needed,have product container or label at hand.

  • P102 Keep out of reach of children.

  • P103 Read label before use

 

Precautionary statements - Prevention

  • P201 Obtain special instructions before use.

  • P202 Do not handle until all safety precautions have been read and understood.

  • P210 Keep away from heat/sparks/open flames/hot surfaces.—— No smoking.

  • P211 Do not spray on an open flame or other ignition source.

  • P220 Keep/Store away from clothing/..../combustible materials.

  • P221 Take any precaution to avoid mixing with combustibles/....

  • P222 Do not allow contact with air.

  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.

  • P230 Keep wetted with ....

  • P231 Handle under inert gas.

  • P232 Protect from moisture.

  • P233 Keep container tightly closed.

  • P234 Keep only in original container.

  • P235 Keep cool.

  • P240 Ground/bond container and receiving equipment.

  • P241 Use explosion-proof electrical/ventilating/lighting/..../equipment.

  • P242 Use only non-sparking tools.

  • P243 Take precautionary measures against static discharge.

  • P244 Keep reduction valves free from grease and oil.

  • P250 Do not subject to grinding/shock/..../friction.

  • P251 Pressurized container: Do not pierce or burn, even after use.

  • P260 Do not breathe dust/fume/gas/mist/vapours/spray.

  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

  • P262 Do not get in eyes, on skin, or on clothing.

  • P263 Avoid contact during pregnancy/while nursing.

  • P264 Wash hands thoroughly after handling.

  • P264 Wash skin thouroughly after handling.

  • P270 Do not eat, drink or smoke when using this product.

  • P271 Use only outdoors or in a well-ventilated area.

  • P272 Contaminated work clothing should not be allowed out of the workplace.

  • P273 Avoid release to the environment.

  • P280 Wear protective gloves/protective clothing/eye protection/face protection.

  • P281 Use personal protective equipment as required.

  • P282 Wear cold insulating gloves/face shield/eye protection.

  • P283 Wear fire/flame resistant/retardant clothing.

  • P284 Wear respiratory protection.

  • P285 In case of inadequate ventilation wear respiratory protection.

  • P231+P232 Handle under inert gas. Protect from moisture.

  • P235+P410 Keep cool. Protect from sunlight.

​Precautionary statements - Response

  • P301 IF SWALLOWED:

  • P304 IF INHALED:

  • P305 IF IN EYES:

  • P306 IF ON CLOTHING:

  • P307 IF exposed:

  • P308 IF exposed or concerned:

  • P309 IF exposed or if you feel unwell:

  • P310 Immediately call a POISON CENTER or doctor/physician.

  • P311 Call a POISON CENTER or doctor/physician.

  • P312 Call a POISON CENTER or doctor/physician if you feel unwell.

  • P313 Get medical advice/attention.

  • P314 Get medical advice/attention if you feel unwell.

  • P315 Get immediate medical advice/attention.

  • P320 Specific treatment is urgent (see .... on this label).

  • P321 Specific treatment (see .... on this label).

  • P322 Specific measures (see .... on this label).

  • P330 Rinse mouth.

  • P331 Do NOT induce vomiting.

  • P332 IF SKIN irritation occurs:

  • P333 If skin irritation or rash occurs:

  • P334 Immerse in cool water/wrap n wet bandages.

  • P335 Brush off loose particles from skin.

  • P336 Thaw frosted parts with lukewarm water. Do not rub affected area.

  • P337 If eye irritation persists:

  • P338 Remove contact lenses, if present and easy to do. Continue rinsing.

  • P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.

  • P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

  • P342 If experiencing respiratory symptoms:

  • P350 Gently wash with plenty of soap and water.

  • P351 Rinse cautiously with water for several minutes.

  • P352 Wash with plenty of soap and water.

  • P353 Rinse skin with water/shower.

  • P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

  • P361 Remove/Take off immediately all contaminated clothing.

  • P362 Take off contaminated clothing and wash before reuse.

  • P363 Wash contaminated clothing before reuse.

  • P370 In case of fire:

  • P371 In case of major fire and large quantities:

  • P372 Explosion risk in case of fire.

  • P373 DO NOT fight fire when fire reaches explosives.

  • P374 Fight fire with normal precautions from a reasonable distance.

  • P376 Stop leak if safe to do so. Oxidising gases (section 2.4) 1

  • P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

  • P378 Use .... for extinction.

  • P380 Evacuate area.

  • P381 Eliminate all ignition sources if safe to do so.

  • P390 Absorb spillage to prevent material damage.

  • P391 Collect spillage. Hazardous to the aquatic environment

  • P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

  • P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

  • P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

  • P302+P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages.

  • P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

  • P302+P352 IF ON SKIN: wash with plenty of soap and water.

  • P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

  • P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.

  • P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

  • P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

  • P305+P351+P338

  • P306+P360 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.

  • P307+P311 IF exposed: call a POISON CENTER or doctor/physician.

  • P308+P313 IF exposed or concerned: Get medical advice/attention.

  • P309+P311 IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.

  • P332+P313 IF SKIN irritation occurs: Get medical advice/attention.

  • P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.

  • P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

  • P337+P313 IF eye irritation persists: Get medical advice/attention.

  • P342+P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

  • P370+P376 in case of fire: Stop leak if safe to Do so.

  • P370+P378 In case of fire: Use .... for extinction.

  • P370+P380 in case of fire: Evacuate area.

  • P370+P380+P375 in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.

  • P371+P380+P375 in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

 

 

Precautionary statements —— Storage

  • P401 Store ....

  • P402 Store in a dry place.

  • P403 Store in a well-ventilated place.

  • P404 Store in a closed container.

  • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

  • P405 Store locked up.

  • P406 Store in corrosive resistant/.... container with a resistant inner liner.

  • P407 Maintain air gap between stacks/pallets.

  • P410 Protect from sunlight.

  • P411 Store at temperatures not exceeding .... oC/....oF.

  • P412 Do not expose to temperatures exceeding 50 oC/ 122 oF.

  • P413 Store bulk masses greater than .... kg/....lbs at temperatures not exceeding .... oC/....oF.

  • P420 Store away from other materials.

  • P422 Store contents under ....

  • P402+P404 Store in a dry place. Store in a closed container.

  • P403+P233 Store in a well-ventilated place. Keep container tightly closed.

  • P403+P235 Store in a well-ventilated place. Keep cool.

  • P410+P403 Protect from sunlight. Store in a well-ventilated place.

  • P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.

  • P411+P235 Store at temperatures not exceeding .... oC/....oF. Keep cool.

Precautionary statements —— Disposal

  • P501 Dispose of contents/container to....

  • P502 Refer to manufacturer/supplier for information on recovery/recycling

Precautionary Statements